On the origins of extractive metallurgy: new evidence from Europe

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Abstract

The beginnings of extractive metallurgy in Eurasia are contentious. The first cast copper objects in this region emerge c. 7000 years ago, and their production has been tentatively linked to centres in the Near East. This assumption, however, is not substantiated by evidence for copper smelting in those centres. Here, we present results from recent excavations from Belovode, a Vinča culture site in Eastern Serbia, which has provided the earliest direct evidence for copper smelting to date. The earliest copper smelting activities there took place c. 7000 years ago, contemporary with the emergence of the first cast copper objects. Through optical, chemical and provenance analyses of copper slag, minerals, ores and artefacts, we demonstrate the presence of an established metallurgical technology during this period, exploiting multiple sources for raw materials. These results extend the known record of copper smelting by more than half a millennium, with substantial implications. Extractive metallurgy occurs at a location far away from the Near East, challenging the traditional model of a single origin of metallurgy and reviving the possibility of multiple, independent inventions.

Introduction

The invention of extractive metallurgy, its location, timing, and origins, are among the restlessly argued matters in prehistoric archaeology. The introduction of metallurgy to prehistoric communities has provided an important chronological backbone for the later prehistory worldwide and has been widely discussed throughout the work of influential scholarship, and recognized as essential for the emergence of complex societies. Such ideas can be traced to the work of Childe, 1944, Childe, 1958, who saw the Near Eastern prehistoric communities as the single inventors of extractive metallurgy. The concept of a single origin was challenged by Renfrew (1969) who argued for multiple inventions of metallurgy in independent centres throughout Eurasia. This debate has since received new field and analytical data, which helped understanding the geological, technological and/or social factors involved in various cultural manifestations of emerging metallurgical activity (cf. Roberts et al., 2009). However, due to the lack of direct evidence of actual smelting from any of the suggested regions of invention, the origins of extractive metallurgy remain hotly contested (Roberts et al., 2009, Thornton et al., 2010).
Importantly, in the studies of ancient metallurgy, metal artefacts have received the lion’s share of the scholarly attention. The structural, chemical and isotopic analysis of artefacts can respectively show the ancient technology of their working and making, and the suggested geological origins of the metal used. However, the story of finished artefacts is only a relatively small part of the whole chaîne opératoire of metallurgy; a typical prehistoric metallurgical site would normally contain a set of various stone tools, ores, charcoal, fragments of technical ceramics and installations (furnaces, crucibles, tuyéres) and various types of slag and other waste products (cf. Rehren and Pernicka, 2008). For a more comprehensive understanding of the technology of metal production and its cultural transmission, the full range of technological debris needs to be analysed and incorporated in archaeometallurgical research (cf. Bachmann, 1982, Craddock, 1995 and literature therein, Renzi et al., 2009, Thornton and Rehren, 2009, Thornton et al., 2009).
This paper contributes to the debate on the origins of extractive metallurgy by presenting remains of copper smelting discovered recently in Belovode, a Vinča culture site in Eastern Serbia. Chemical, structural and provenance analyses of numerous finds including copper slag, geological and archaeological minerals, a copper metal droplet, and several malachite beads demonstrate consistent and coexisting metal smelting and malachite bead manufacturing activities at the site. Significantly, the analyses indicated that different sources were exploited for raw materials for copper smelting and bead making, respectively, suggesting a good knowledge of their relevant material properties. The first smelting event so far documented at Belovode occurs at c. 5000 BC, which makes it the earliest securely dated record of extractive metallurgy, anywhere. This event occurs at a location far from the Near East and in a region exceptionally rich in early metal artefacts, thereby challenging the model of a single origin of extractive metallurgy.

Section snippets

Development of copper metallurgy in Eurasia

The use of geological copper sources is known from two technologically rather independent industries: minerals such as native copper, malachite and azurite were used for millennia for bead and pigment making using ‘cold’ lithic technologies, before the ‘hot’ metallurgical production of copper metal by smelting/melting began. Indeed, the earliest interest in copper minerals was due to their distinctive optical properties: the use of green and blue beads and pigments goes back to the eleventh

Early copper smelting

The identification of early smelting evidence is fraught with difficulties. Craddock, 1995, Craddock, 2009 presents the idea of ‘slagless’ metallurgy based on very pure copper carbonate ores which, in principle, may leave virtually no slag, and summarises the evidence for the earliest European copper smelting with ‘slag heaps’ weighing in the tens of grams in total. Bourgarit (2007:10) further explores this concept arguing that “slagless” metallurgy usually occurs in domestic contexts, while

Vinča culture and copper metallurgy

The Vinča culture is a later Neolithic/early Chalcolithic phenomenon which lasted for 700 years in the largest part of the northern and central Balkans, spreading across an area which includes present-day Serbia, the Romanian Banat, parts of Romanian Oltenia, western Bulgaria, northern Macedonia and eastern parts of Slavonia and Bosnia (Garašanin, 1973). It shows strong links with the contemporaneous Kodžadermen-Gumelniţa-Karanovo VI cultural complex in Bulgaria and Dimini V in Greece,

Materials: selection and sampling

All materials discovered in the Belovode excavation, including the geological source nearby this site, were subject to selection conducted in the Depot for Prehistory at the National Museum Belgrade. Out of c. 400 samples we initially selected 34 and grouped them on the basis of their macroscopic characteristics as slags, geological and archaeological minerals (Belovode and Ždrelo), copper ores, artefacts (numerous malachite beads and a droplet of copper metal) and green-stained ceramic sherds.

Composition and structure of slag

All slag samples from Belovode show consistency in their mineralogy, presenting various newly formed phases: prills of metallic copper, cuprite, spinels and delafossite in a mostly glassy siliceous matrix. The copper metal is free of metallic impurities above c. 0.1 wt% and solidified from a fully molten stage, as indicated by the formation of large alpha copper dendrites with the copper–copper oxide eutectic in the interstices (Fig. 5).
Larger areas of massive cuprite, most likely formed from

Discussion

Our results present new insights into the beginning of extractive metallurgy. The identification of smelting activities in the Vinča culture settlement Belovode provides the earliest documented proof of pyrometallurgical copper extraction to date, at the turn of the sixth to the fifth millennium BC.
This is more than half a millennium earlier than previously published secure evidence for copper smelting from the Near East and the Balkans (Hauptmann, 2007, Ryndina et al., 1999). Importantly, the

Conclusion

The research presented here documents the earliest sound evidence for copper smelting known so far, anywhere, consisting of slag droplets rich in typical gangue elements together with molten copper metal. We note the absence of dedicated ceramic vessels such as crucibles or furnace installations from our observations, leaving room for a potential ‘hole in the ground’ model for the predominantly solid-state reduction step (represented here by the small droplets of slag which may have formed in

Acknowledgements

The initial work was done as part of MR’s MSc in Technology and Analysis of Archaeological Materials, which is continuing as doctoral research at the UCL Institute of Archaeology. ThR and MR acknowledge with gratitude the substantial financial support of this research first from the European Union for the Marie Curie action project IoASCA, under contract MEST-CT-2004-514509, Tokyo Foundation, and the Republic of Serbia (Fund for Young Talents, Ministries of Science and of Culture), and more

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